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Aromatic compounds bearing one or more powerful electron-withdrawing substituents in addition to a leaving group can occasionally undergo nucleophilic substitution in place of electrophilic substitution. The standard mechanisms of $mathrm S _ mathrm N two$ and $mathrm S _ mathrm N 1$ reactions are impossible because of the $s p^ 2 $ -hybridization for the carbons of a benzene ring, but a mechanism that includes nucleophilic addition followed by elimination, called $S_ mathrm N mathrm Ar $ (nucleophilic aromatic substitution), is feasible.
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